Alexandra, Princess of Wales (1844–1925), born Princess Alexandra of Denmark, married Albert Edward, Prince of Wales, the future King Edward VII, in 1863, making her one of the most photographed royal figures of the Victorian era. This albumen carte de visite was produced by the Paris studio of Augustin Aimé Joseph Le Jeune, successor to Count Sergei Lvovich Levitsky at 22, rue de Choiseul, and is dated October 1869 at Saint-Cloud, placing it during a French imperial court visit.

The Princess is seated in three-quarter length against a softly painted atmospheric backdrop, wearing a full-skirted dark velvet gown with an elaborately embroidered bodice panel trimmed in light lace. A high black collar rises at the throat, and the sleeves terminate in wide lace cuffs adorned with a cluster of white fabric flowers tied with small dark ribbons. Her dark hair is styled in tight ringlet curls framing her face, and she holds a velvet accessory in her lap, her direct gaze calm and composed.

Le Jeune, active in Paris during the 1860s and 1870s, operated at 22, rue de Choiseul and carried the imperial warrant as photographer to His Imperial Highness the Prince Imperial, one of the most prestigious photographic appointments of the French Second Empire. The studio's royal and aristocratic clientele made it a leading address for formal portraiture in this period, and surviving examples of its work are held in major French national collections including the Musée d'Orsay.

The reverse bears a purple ink stamp reading "LE JEUNE / Photographe Breveté / de S.A. le Prince Impérial / St Cloud – Octobre 1869 / Ancienne Mon. Levitsky," and is inscribed in pencil at the upper edge "Princess of Wales" (Princess of Wales). A crown and ribbon device is printed on the recto mount below the image.